DETECTION OF ETHYL ALCOHOL PRESENT IN GIVEN ORGANIC COMPOUND

Experiment No. 10: DETECTION OF ETHYL ALCOHOL PRESENT IN GIVEN ORGANIC COMPOUND
OBJECTIVE:
TO DETECT THE FOREIGN ELEMENT PRESENT IN GIVEN ORGANIC COMPOUND
APPARATUS REQUIRED
  1. Watch glass
  2. Tong
  3. Burner
  4. Porcelain basin
  5. Beaker
  6. Test tube
CHEMICALS REQUIRED
  • Given organic sample
  • Blue and red litmus paper
  • Acetic acid
  • H2SO4
  • K2Cr2O7
  • NaOH
THEORY

Organic compounds are hydrocarbon and their derivatives. They are mainly made up of two parts- alkyl and functional group part. The functional group is defined as the atom or group of atoms that determines the characteristic properties of the organic compound. Some examples of functional groups are -OH, -CHO, -COOH, etc.

PROCEDURE

First of all, a preliminary test was performed. Then confirmatory test was done to identify the given organic compound.

OBSERVATION

1. Preliminary test:

a. Solubility: Soluble in water
b. Odour: Spiritious
c. Colour: Colourless
d. Litmus paper test: Neutral
e. Residue test :

ExperimentObservationInference
Residue/Evaporation test:

A few drops of the solution were evaporated
on the watch glass over the water bath.

No residue

May be ethyl aclohol
Confirmatory Test
Test of ethyl alcohol
ExperimentObservationInference
1. Esterification test:

2 ml of original solution was taken in
a clean and dry test tube and 2 ml of
glacial acetic acid solution was added to it.
Then, 1 ml of conc. H2SO4 was added and then heated.


A fruity smell of ester was observed.


Presence of ethyl alcohol
2. Oxidation test:

2 ml of original solution was taken in
a clean and dry test tube and 2 ml of potassium dichromate solution was added to it. Then, 1 ml of conc. H2SO4 was added and then
heated gently.

The orange colour of the potassium dichromate solution turned to green.

Presence of ethyl alcohol.
3. Iodoform test:

2 ml of the original solution was taken in a
clean and dry test tube and a few drops of
iodine solution was added to it followed by
NaOH solution dropwise till brown colour disappeared and warmed over the water bath
at 70°C.

A yellow crystalline precipitate of iodoform was formed.

Presence of ethyl alcohol
Reactions involved
RESULT

Hence, ethyl alcohol was found in the given solution.

CONCLUSION

Hence, organic compounds can be tested using specific reagents.

PRECAUTION
  1. Apparatus should be handled carefully.
  2. The sample should be taken in small amounts.
  3. Heating should be done carefully.

Structure: CH3CH2OH
IUPAC name: Ethanol
Common name: Ethyl alcohol

References:
Mishra, AD, et al. Pioneer Chemistry. Dreamland Publication.
Mishra, AD et al. Pioneer Practical Chemistry. Dreamland Publication
Wagley, P. et al. Comprehensive Chemistry. Heritage Publisher & Distributors Pvt. Ltd.

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